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Hydrothermal synthesis of a nano-rod mercury(ii) metal-ligand coordination compound |
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| Authors: | Y Hanifehpour A Khataee Sang Woo Joo Bong-Ki Min |
| Institution: | 1. School of Mechanical Engineering, WCU Nano Research Center, Yeungnam University, Gyongsan, South Korea 2. Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran 3. Center for Research Facilities, Yeungnam University, Gyongsan, South Korea |
| Abstract: | A novel nano-rod mercury(II) coordination compound Hg (BINH)I2] (1), (BINH is the abbreviation of benzylideneisonicotinohydrazide) is synthesized by a hydrothermal method that produces the coordination compound at a nanosize level. The new nanostructure is characterized by scanning electron microscopy, powder X-ray diffraction, elemental analysis, and IR spectroscopy. Compound 1 was structurally characterized by single crystal X-ray diffraction and the single-crystal structure of this complex shows that each mercury(II) center is four-coordinated with two N-donor atoms from tow BINH ligands and tow iodo anions. Self-assembly of this complexes is pereformed by CH?I and π-π stacking interactions. The supramolecular features in these complexes are controlled by weak directional intermolecular interactions. |
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