Organoruthenium derivative of the cyclic [H7P8W48O184]33- anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- |
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| Authors: | Mal Sib Sankar Nsouli Nadeen H Dickman Michael H Kortz Ulrich |
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| Institution: | Jacobs University Bremen, School of Engineering and Science, 28725 Bremen, Germany. |
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| Abstract: | Reaction of Ru(p-cymene)Cl2]2 with H7P8W48O184]33- (P8W48) in aqueous acidic medium results in the organometallic derivative {K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor. |
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