| 呋喃甲醛缩二乙撑三胺希夫碱铜配合物的合成及结构(英) |
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| 引用本文： | 杜桂香,王伟,李珺,张逢星.呋喃甲醛缩二乙撑三胺希夫碱铜配合物的合成及结构(英)[J].无机化学学报,2005,21(6):938-940. |
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| 作者姓名： | 杜桂香 王伟 李珺 张逢星 |
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| 作者单位： | 西北大学化学系/陕西省物理无机化学重点实验室,西安,710069 |
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| 基金项目： | 陕西省自然科学基金资助项目(No.HF0125)，陕西省教委基金项目(No.01JK078) |
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| 摘 要： | A novel copper(Ⅱ) complex CuL(NO3)2(where L=N,N′-bis(furaldehyde)-diethylenetriamine) was synthesized and characterized by X-ray crystallography analysis. The crystal belongs to monoclinic, space group C2/c with cell parameters a=1.924 0(6) nm, b=0.792 8(3) nm, c=2.504 1(8) nm, β=111.163(5)°, and Z=8. The coordination geometry around Cu(Ⅱ) is a distorted trigonal-bipyramid，and one-dimensional chain is formed through intermolecular hydrogen bonds. CCDC: 255629.
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| 关 键 词： | 呋喃甲醛 希夫碱 铜配合物 晶体结构 |
| 收稿时间： | 2004/11/15 0:00:00 |
| 修稿时间： | 2005/1/13 0:00:00 |
Synthesis and Structure of a New Copper(Ⅱ) Complex with Schiff Base Derived from Furaldehyde and Diethylenetriamine |
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| DU Gui-Xiang,WANG Wei,LI Jun and ZHANG Feng-Xing.Synthesis and Structure of a New Copper(Ⅱ) Complex with Schiff Base Derived from Furaldehyde and Diethylenetriamine[J].Chinese Journal of Inorganic Chemistry,2005,21(6):938-940. |
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| Authors: | DU Gui-Xiang WANG Wei LI Jun and ZHANG Feng-Xing |
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| Abstract: | A novel copper(Ⅱ) complex CuL(NO3)2 (where L=N,N'-bis(furaldehyde)-diethylenetriamine) was synthesized and characterized by X-ray crystallography analysis. The crystal belongs to monoclinic, space group C2/c with cell parameters a= 1.924 0(6) nm, b=0.792 8(3) nm, c=2.504 1(8) nm, β=111.163(5)°, and Z=8. The coordination geometry around Cu(Ⅱ) is a distorted trigonal-bipyramid, and one-dimensional chain is formed through intermolecular hydrogen bonds. CCDC: 255629. |
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| Keywords: | furaldehyde Schiff base copper(Ⅱ) complex crystal structure |
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