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Performance of ferrite fillers on electrical behavior of polymer nanocomposite electrolyte
Authors:Kamlesh Pandey  Mrigank Mauli Dwivedi  Markandey Singh  SL Agrawal
Institution:1. National Centre of Experimental Mineralogy and Petrology , University of Allahabad , Allahabad-211 002 , Uttar Pradesh , India kp542831@gmail.com;3. National Centre of Experimental Mineralogy and Petrology , University of Allahabad , Allahabad-211 002 , Uttar Pradesh , India;4. Department of Physics , A.P.S. University , Rewa 486003 , Madhya Pradesh , India
Abstract:Dispersal of nanofillers in polymer electrolytes have shown to improve the ionic properties of Polyethylene oxide (PEO)-based polymer electrolytes in recent times. The effects of different nanoferrite fillers (i.e., Al–Zn ferrite, Mg–Zn ferrite, and Zn ferrite) on the electrical transport properties have been studied here on the composite polymer electrolyte system. The interaction of salt/filler with electrolyte has been investigated by XRD studies. SEM image and infrared spectral studies give an indication of nanocomposite formation. In conductivity studies, all electrolyte systems are seen to follow universal power law. Composition dependence (with ferrite filler) gives the maximum conductivity in 93PEO–7NH4SCN]: X ferrite (where X?=?2% in Al–Zn ferrite, 1% Mg–Zn ferrite, and 1% Zn ferrite) system.
Keywords:proton conductor  polymer nanocomposite electrolytes  polymer composite electrolyte  PEO  ferrite filler
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