1. Department of Physics , University of Edinburgh , Mayfield Road, Edinburgh , Scotland;2. Université du Maine, Faculté des Sciences, Laboratoire P.E.C. , U. A. no. 807 C.N.R.S., 72017, Le Mans , Cedex , France
Abstract:
A high-resolution X-ray scattering study of the influence of impurities on the cubic to tetragonal first-order phase transition of KMnF3 is presented. It is shown that Ca++ ions substituted for Mn++ or Na+ ions substituted for K+ ions at a 1% concentration can influence drastically both the nature and the critical fluctuations of this transition. A qualitative attempt of interpretation in terms of random stress effects is presented.