| 梯形结构有机锡配合物{[(p-MeC6H4CH2)2Sn]2(O)(Cl)OC2H5}2的合成和晶体结构 |
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| 引用本文： | 王剑秋,张复兴,邝代治,冯泳兰,许志锋,陈志敏.梯形结构有机锡配合物{[(p-MeC6H4CH2)2Sn]2(O)(Cl)OC2H5}2的合成和晶体结构[J].无机化学学报,2007,23(5):871-874. |
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| 作者姓名： | 王剑秋 张复兴 邝代治 冯泳兰 许志锋 陈志敏 |
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| 作者单位： | 衡阳师范学院化学与材料科学系,衡阳,421008 |
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| 基金项目： | 湖南省教育厅科研项目;项目和湖南省自然科学基金 |
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| 摘 要： | The title compound {(p-MeC6H4CH2)2Sn]2(O)(Cl)OC2H5}2 was synthesized by the reaction of bis(p-met-hylbenzyl)tin dichloride with KOH in ethanol. The crystal structure of the complex has been determined by X- ray diffraction. The crystal belongs to monoclinic, space group P21/c with a=1.114 0(19) nm, b=2.423 1(3) nm, c=2.521 1(3) nm, β=99.398(3)°, V=6.714(16) nm3, Z=4, Dc=1.493 g·cm-3, μ(Mo Kα)=15.94 cm-1, F(000)=3 024, R1=0.049 9, wR=0.101 7. The crystal structure shows that the coordination geometry of tin is a distorted trigonal bipyramid, and the ladder-like structure is shaped by three Sn2O2 planar four-membered rings. CCDC: 639682.
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| 关 键 词： | 有机锡配合物 合成 晶体结构 |
| 文章编号： | 1001-4861(2007)05-0871-04 |
| 修稿时间： | 2006-11-27 |
Synthesis and Crystal Structure of the Ladder Organotin Complex {[(p-MeC6H4CH2)2Sn]2(O)(Cl)OC2H5}2 |
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| WANG Jian-Qiu,ZHANG Fu-Xing,KUANG Dai-Zhi,FENG Yong-Lan,XU Zhi-Feng and CHENG Zhi-Min.Synthesis and Crystal Structure of the Ladder Organotin Complex {[(p-MeC6H4CH2)2Sn]2(O)(Cl)OC2H5}2[J].Chinese Journal of Inorganic Chemistry,2007,23(5):871-874. |
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| Authors: | WANG Jian-Qiu ZHANG Fu-Xing KUANG Dai-Zhi FENG Yong-Lan XU Zhi-Feng and CHENG Zhi-Min |
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| Institution: | Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008,Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008 and Department of Chemistry and Material Science, Hengyang Normal University, Hengyang, Hunan 421008 |
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| Abstract: | |
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| Keywords: | organotin complex synthesis crystal structure |
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