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| Concise Synthesis of(±)-epi-Chrysotricine | |
| 作者姓名： | Guang Xing WANG Jing Xin ZHANG Shu Feng CHEN Xiao Tian LIANG* Institute of Materia Medica Chinese Academy of Medical Sciences and Peking Union Medical College Beijing |
| 作者单位： | Guang Xing WANG，Jing Xin ZHANG，Shu Feng CHEN，Xiao Tian LIANG* Institute of Materia Medica，Chinese Academy of Medical Sciences and Peking Union Medical College，Beijing 100050 |
| 基金项目： | the National Research Center for Analysis of Drugs and Metabolites for recording NMR and MS data. This project was partially fo |
| 摘 要： | Chrysotricine 1 was isolated from the Chinese herb medicine Hedyotis Chrysotricha and was shown to possess antitumor activity1. Its structure has been elucidated as a novel zwitterionic (-carboline alkaloid containing a 2,2,5-trisubstituted tetrahydrofuranyl group. The (-carboline compounds have attracted considerable attraction in recent years because of their promising and intriguing biological activities2. Recently, we have established the absolute configuration of chrysotricine by the fir… |
| 关 键 词： | (±)-epi-chrysotricine dilithium salt of harman VO(acac)2 TBHP oxidation |
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