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A Chiral Phosphorous Derivatizing Agent for the Determination of the Enantiomeric Excess of Chiral Alcohols, Amines by ~(31)P NMR
Authors:Kang Ying LI  Zheng Hong ZHOU  Chi Hung YEUNG  Chu Chi TANG State Key Laboratory of Elemento-Organic Chemistry  Nankai University  Tianjin Laboratory of Chiral Technology and
Affiliation:Kang Ying LI1,Zheng Hong ZHOU1,Chi Hung YEUNG2,Chu Chi TANG* 1State Key Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin 300071 2Laboratory of Chiral Technology and Department of Applied Biology and Chemical Technology,The Hong Ko
Abstract:A chiral phosphorous derivatizing agent prepared from PCl3 and (S)-BINOL was described. It is used to determine the enantiomeric excess of chiral alcohols and amines by 31P NMR.
Keywords:Chiral phosphorous   derivation   chiral alcohols   chiral amines   enantiomeric excess   asymmetric induction.
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