| 金纳米粒子在平整硅基表面上的组装 |
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| 引用本文： | 胡瑞省,刘善堂,朱梓华,朱涛,刘忠范.金纳米粒子在平整硅基表面上的组装[J].物理化学学报,2000,16(3):202-206. |
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| 作者姓名： | 胡瑞省 刘善堂 朱梓华 朱涛 刘忠范 |
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| 作者单位： | Center for Nanoscale Science and Technology,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871 |
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| 基金项目： | 国家自然科学基金资助项目(29803002)The
Project Supported by NSFC(29803002) |
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| 摘 要： | 采用水相硅烷化方法，将３－氨基丙基－三甲氧基硅烷（ＡＰＳ）组装在湿化学法处理的单晶硅表面上。接触角、原子力显微镜（ＡＦＭ）、Ｘ射线光电子能谱（ＸＰＳ）表征结果显示得到了平整均匀的具有氨基表面的自组装膜。ＳＥＭ观察表明，１６ｎｍ的金纳米粒子可以在上述氨基表面上形成均匀的亚单层排布，得到了具有Ａｕ纳米粒子／ＡＰＳ／Ｓｉ形成的纳米复合结构，进一步的处理可以使金纳米粒子在表面上的排列由随机趋于有序化。
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| 关 键 词： | 金纳米粒子 硅烷化 组装 |
| 收稿时间： | 1999-05-17 |
| 修稿时间： | 1999年5月17日 |
Assembling Gold Nanoparticles on Ultrasmooth Silicon Surface |
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| Hu Ruisheng,Liu Shantang,Zhu Zihua,Zhu Tao,LIU Zhongfan.Assembling Gold Nanoparticles on Ultrasmooth Silicon Surface[J].Acta Physico-Chimica Sinica,2000,16(3):202-206. |
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| Authors: | Hu Ruisheng Liu Shantang Zhu Zihua Zhu Tao LIU Zhongfan |
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| Institution: | Center for Nanoscale Science and Technology,College of Chemistry and Molecular Engineering,Peking University,Beijing 100871 |
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| Abstract: | Chemically-wet treated silicon substrate was modified with self-assembled monolayer of 3-aminopropyl-trimethylsilane by aqueous phase silanization,giving an ultrasmooth and homogenous surface terminated with amino groups.Colloidal gold nanoparticles (15.7± 2.0 nm)were adsorbed on such a surface with a submonolayer coverage and a random particle distribution.Increases in local surface coverage and packing order were induced by capping the assembled gold nanoparticles with alkanthiol molecules in an enthanolic solution. |
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| Keywords: | Gold nanoparticles Silanization Assembly |
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