One-dimensional void-space arrays constructed from a coordination polymer with bowl-like frameworks of cavitands |
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| Authors: | Tadokoro Makoto Mizugaki Shin Kozaki Masatoshi Okada Keiji |
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| Institution: | Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan. tadokoro@sci.osaka-cu.ac.jp |
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| Abstract: | A one-dimensional coordination polymer of Mn(II)(hfac)2] bridged by new bowl-like ligands of cavitands was prepared and the crystal structure was determined by X-ray crystal analysis. Ethyl acetate molecules are necessarily included as guest molecules in each of the void-space cavities of the cavitands, and then are held by weak interaction forces. |
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