Kinetic studies of thiolane synthesis from tetrahydrofurane and H2S |
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Authors: | V Yu Mashkin I V Desyatov and A V Mashkina |
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Institution: | (1) Institute of Catalysis, 630090 Novosibirsk, Russia |
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Abstract: | Kinetic studies of tetrahydrofuran reaction with H2S were carried out in a flow-circulation reactor. Presumably, the reaction takes place through dissociative chemisorption of reactants and the interaction of surface structures formed to produce thiolane and water. A kinetic equation that agrees with the suggested mechanism has been derived.
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