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The effect of a sulphur bridge on the photochromic properties of indeno-fused naphthopyrans
Authors:Paulo J Coelho  Maria A Salvador  MManuel Oliveira  Luis M Carvalho
Abstract:The synthesis of four new 2,2-diphenyl-2H-naphtho1,2-b]pyrans with a fused indeno group at the f face and a sulphur junction between the 2,2-phenyl groups is described. The photochromic properties in solution of these novel compounds were investigated under continuous irradiation. Compared to known indeno-fused naphthopyrans, these new compounds showed a significant bathochromic shift in the spectra of the open forms, faster ring closure kinetics and an expected decrease in the colourabilities.
Keywords:Photochromism  Naphthopyrans  Spectrokinetics  Heterocycles  Spiro[thioxanthene-naphthopyrans]
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