Crystal structure of the reaction product of copper(II) nitrate with α-(3,3-Dimethyl-3,4-dihydro-1-isoquinolyl)hydroxy-iminoacetonitrile [Cu3(μ3-OH)(μ-L)3(NO3)2(H2O)] · 2H2O |
| |
| Authors: | V I Sokol V V Davydov N Yu Merkur&#;eva E I Polyakova Yu V Shklyaev and V S Sergienko |
| |
| Institution: | (1) Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia;(2) Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, 117198, Russia;(3) Institute of Technical Chemistry, Ural Division, Russian Academy of Sciences, ul. Lenina 13, Perm, 614600, Russia |
| |
| Abstract: | The coordination compound Cu3(μ3-OH)(μ-L)3(NO3)2(H2O)] · 2H2O (I), where L is the α-(3,3-dimethyl-3,4-dihydro-1-isoquinolyl)hydroxyiminoacetonitrile anion, has been synthesized. The crystal
and molecular structure of I was determined by X-ray diffraction (Enraf-Nonius CAD4, MoK
α radiation, graphite monochromator, ω-scan mode, 2θmax = 49.96°, 7673 unique reflections, a = 12.745(3) ?, b = 13.726(3) ?, c = 28.835(6) ?, β = 93.44(3)°, V = 5035.2(17) ?3, Z = 4, space group P21/c). In the trimer complex I, the copper atoms are combined by a bridging hydroxy group. The copper atoms are additionally linked pairswise by three tridentate
chelating bridging organic anions coordinated to the Cu(II) atoms by the N and O atoms of the deprotonated oxime group and
by the N atom of the dihydroisoquinoline moiety.
Original Russian Text ? V.I. Sokol, V.V. Davydov, N. Yu. Merkur’eva, E.I. Polyakova, Yu.V. Shklyaev, V.S. Sergienko, 2007,
published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52, No. 10, pp. 1643–1652. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
