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Simultaneous and Selective Detection of Environment Hazardous Metals in Water Samples by Using Flower and Christmas Tree Like Cerium Hexacyanoferrate Modified Electrodes
Authors:Mani Sivakumar  Shen‐Ming Chen  Chi‐Chang Hu
Institution:1. Electro analysis and Bio electrochemistry Lab, Department of Chemical Engineering and Biotechnology, National Taipei University of Technology, No.1, Section 3, Chung‐Hsiao East Road , Taipei 106, Taiwan (R.O.C). Fax: +886?2270?25238;2. Tel: +886?2270?17147;3. Laboratory of Electrochemistry & Advanced Materials, Department of Chemical Engineering, National Tsing Hua University, HsinChu 30013, Taiwan(R.O.C).
Abstract:We report facile, template‐free, surfactant‐less flower and Christmas tree‐like cerium hexacyanoferrate (CeHCF) modified electrodes for simultaneous measurement of environmentally hazardous metals. The hierarchical growth of CeHCF on electrode surface was controlled by electrodeposition time at constant potential. This CeHCF modified electrode exhibits a prominent electrocatalytic activity towards detection of heavy metal ions such as cadmium (Cd), copper (Cu), lead (Pb) and mercury (Hg). The peaks are separated well at CeHCF modified electrode. Well separated peaks for the detection of these heavy metals in lake and tap water samples indicating CeHCF modified electrode as successful electrode for the reported sensor.
Keywords:Voltammetric  Cerium hexacaynoferrate  Heavy metal ions  and water samples
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