Reactions of copper acetylides. Structure of (π-C5H5)Ru(PPh3)2 (CCPh)CuCl,and new syntheses of transition metal cluster compounds |
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| Authors: | MI Bruce OMAbu Salah RE Davis NV Raghavan |
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| Institution: | Department of Inorganic Chemistry, The University, Bristol BS8 1TS Great Britain;Department of Chemistry, University of Texas at Austin, Austin, Texas 78712 U.S.A. |
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| Abstract: | In contrast to a related iron—copper compound, the complex (π-C5H5)Ru(PPh3)2(C2Ph)CuCl is shown to be monomeric, and contains linear dicoordinate copper(I); the reactions of this and similar complexes with metal carbonyls are sources of new mixed-metal clusters, such as (π-C5H5)Fe2 Ru(C2Ph)(CO)6 (PPh3). |
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