Reactions of methyl fluorosulphonate and triethyloxonium tetrafluoroborate with metal complexes |
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Authors: | C. Eaborn N. Farrell J.L. Murphy A. Pidcock |
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Affiliation: | School of Molecular Sciences, University of Sussex, Brighton BN1 9QJ Great Britain |
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Abstract: | ![]() Methyl fluorosulphonate and triethyloxonium tetrafluoroborate (which is less reactive) have been found to give four distinct types of reaction with transition metal complexes, viz. (a) halogen abstraction, (b) oxidative-addition, (c) alkylation of the coordinated ligands, and (d) oxidation at the metal atom. |
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