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Cationic cyclic carbene or carbon-bonded ylide complexes of iridium(III) and platinum(II)
Authors:P.J. Fraser  W.R. Roper  F.G.A. Stone
Affiliation:Department of Inorganic Chemistry, The University, Bristol BS8 1TS Great Britain
Abstract:2-Chloro-4-methylthiazole, 2-chlorobenzoxazole and 2-chlorobenzthiazole oxidatively add to both [IrCl(CO)(PMe2Ph)2] and [Pt(PhCHCHPh)(PEt3)2]; protonation of the products at nitrogen produces cationic carbene complexes.
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