The preparation of perfluorinated carboxylic esters and perfluoro carbonates |
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Authors: | PG Johnson B Tittle |
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Institution: | Imperial Chemical Industries, Mond Division, The Heath, Runcorn, Cheshire Gt. Britain |
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Abstract: | Aliphatic perfluorinated carboxylic esters have been prepared by two methods; (i) the reaction of the potassium salt of perfluoro 3-ethyl pent-3-ol, KOC(C2F5)3, with perfluoro acid chlorides RfCOCl, to yield perfluorinated esters of composition RfCOOC(C2F5)3, and (ii) the reaction of carbonyl chloride or thionyl chloride with a mixture of the potassium salt KOC(C2F5)3 and perfluoro acid salts of the general formula KOCORf in a polar solvent. The product ester has the composition RfCOOC(C2F5)3, and in this instance carbon dioxide or sulphur dioxide is liberated during the reaction. A qualitative study of the thermal decomposition of a perfluoro ester has been made.A tertiary perfluoro carbonate of composition (C2F5)2CF3CO]2CO has been prepared by the reaction of phosgene with the potassium salt KOC(C2F5)2CF3 in a polar solvent. The intermediate acid chloride (C2F5)2CF3COCOCl can be isolated. |
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