Homolytic reactions of polyfluoroaromatic compounds V. The reaction of pentafluorophenyl radicals with fluorobenzene |
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Authors: | J.P.B. Sandall R. Bolton G.H. Williams |
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Affiliation: | Bedford College, (University of London), Regent''s Park, London NW1 4NS Gt. Britain |
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Abstract: | The arylation of fluorobenzene with pentafluorophenyl radicals obtained by the reaction of the corresponding aniline with pentyl nitrite is described. The reaction involves attact at the 2t?-,3t?-and 4t?-positions. The composition of the mixture and the nature of its components were determined by 19F NMR spectroscopy and were confirmed by gas-liquid chromatography. |
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