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Trifluoromethylperoxyphoshoryl difluoride,CF3OOPOF2 and trifluoromethoxyphosphoryl difluoride,CF3OPOF2
Authors:Peter A. Bernstein  Darryl D. Desmarteau
Affiliation:Department of Chemistry, Northeastern University, Boston, Mass. 02115 U.S.A.
Abstract:
The new compounds CF3OOPOF2 and CF3OPOF2 have been prepared by the reaction of trifluoromethyl-hydroperoxide, CF3OOH, with μ-oxo-bis-(phosphoryl difluoride), P2O3F4, and difluorophosphine-μ-oxo-phosphoryl difluoride, P2O2F4. Infrared and NMR spectra, physical properties and some chemical reactions are reported for the compounds.
Keywords:
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