Trifluoromethylperoxyphoshoryl difluoride,CF3OOPOF2 and trifluoromethoxyphosphoryl difluoride,CF3OPOF2 |
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Authors: | Peter A. Bernstein Darryl D. Desmarteau |
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Affiliation: | Department of Chemistry, Northeastern University, Boston, Mass. 02115 U.S.A. |
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Abstract: | ![]() The new compounds CF3OOPOF2 and CF3OPOF2 have been prepared by the reaction of trifluoromethyl-hydroperoxide, CF3OOH, with μ-oxo-bis-(phosphoryl difluoride), P2O3F4, and difluorophosphine-μ-oxo-phosphoryl difluoride, P2O2F4. Infrared and NMR spectra, physical properties and some chemical reactions are reported for the compounds. |
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