Preparation and chemistry of stable azidoiodinanes: 1-Azido-3,3-bis(trifluoromethyl)-3-(1H)-1,2-benziodoxol and 1-Azido-1,2-benziodoxol-3-(1H)-one |
| |
| Authors: | Viktor V Zhdankin Chris J Kuehl Alexei P Krasutsky Mark S Formaneck Jason T Bolz |
| |
| Institution: | Chemistry Department, University of Minnesota-Duluth, Duluth, Minnesota 55812 USA |
| |
| Abstract: | Azidoiodinanes 2,4,6 can be prepared from benziodoxols 1,3 and trimethylsilyl azide in the form of stable, crystalline compounds. These compounds are potentially useful reagents for electrophilic azidonation of organic substrates. For example, reaction of azide 6 with cyclohexene affords 2-azidocyclohexanone 7 in moderate yield. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
