Mechanism of proton transfer from 2-nitrohexafluoropropane to amines |
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| Authors: | P. M. Borodin N. S. Golubev G. S. Denisov N. A. Safarov |
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| Affiliation: | (1) Institute of Physics, State University, Leningrad, USSR |
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| Abstract: | ![]()
According to the analysis of NMR kinetic data, the proton transfer from the CH-acid 2-nitrohexafluoropropane to trioctylamine occurs in a hydrogen-bonded complex. The value of the kH/kD ratio ( 6) and the linearity of the ln k vs. T–1 dependence indicate a classical mechanism of the process.
              2-   .      .     ,  .   kH/kD 6  .
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