Arrayed CNx NT–RuO2 nanocomposites directly grown on Ti-buffered Si substrate for supercapacitor applications |
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Institution: | 1. Institute for Nanoscience and Technology, Sharif University of Technology, Tehran, Iran;2. Department of Chemistry, Sharif University of Technology, Azadi Avenue, Tehran 11155-9516, Iran |
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Abstract: | Significant enhancement in supercapacitor performance has been achieved via a new RuO2 nanocomposite materials prepared by direct ruthenium sputtering on arrayed multi-walled carbon nanotubes supported by Ti-buffered Si wafer. XPS, HRTEM and SAED analyses reveal that as-prepared nanoparticles have a crystalline Ru metal core with RuO2 oxide coating. The nanocomposites convert to RuO2–CNx NTs with subsequent electrochemical cycling. At present, well-dispersed and strongly adhered RuO2 NPs have been densely populated on CNx NTs to obtain the overall specific capacitance (1380 F/g-RuO2), charging–discharging rate (up to 600 mV/s) and operation stability (5000 cycles). Thus, RuO2–CNx NTs nanocomposites would make a promising candidate for use in next-generation high efficiency miniaturized supercapacitors directly fabricated on Si substrate. |
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