Application of the ΔΛ isomerism of octahedral metal complexes as a chiral source in photochemistry |
| |
| Affiliation: | 1. Department of Earth and Planetary Science, Graduate School of Science, The University of Tokyo, Tokyo 113-0033, Japan;2. PRESTO, Japan Science and Technology Agency, Chiba 277-8561, Japan;3. Department of Chemistry, Faculty of Science, Ochanomizu University, Tokyo 112-8610, Japan;4. CREST, Japan Science and Technology Agency, Tokyo 103-0027, Japan;1. Department of Organic Chemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, Marulićev trg 19, 10 000 Zagreb, Croatia;2. Department of General and Inorganic Chemistry, Institute of Chemistry, Faculty of Engineering, University of Pannonia, P.O.B. 158, Veszprém H-8201, Hungary;3. NMR Center, Rudjer Bošković Institute, Bijenička cesta 54, 10 000 Zagreb, Croatia;1. Department of Chemistry, Taras Shevchenko National University of Kyiv, 12 L. Tolstoho Str., Kyiv 01033, Ukraine;2. Division of Functional Materials Chemistry, SSI “Institute for Single Crystals” of National Academy of Science of Ukraine, 60 Lenina Ave., Kharkiv 61001, Ukraine;3. Department of Chemistry, V. N. Karazin Kharkiv National University, 4 Svobody Sq, Kharkiv 61122, Ukraine;1. School of Science, RMIT University, GPO Box 2476, Melbourne VIC-3001, Australia;2. The Centre for Advanced Materials and Industrial Chemistry (CAMIC), School of Science, RMIT University, GPO Box 2476, Melbourne VIC-3001, Australia;1. Institute of Physics, University of Sao Paulo, Brazil;2. Institute of Fluid Mechanics, Technische Universität Dresden, Germany |
| |
| Abstract: | Photochemical studies on the use of chiral metal complexes in homogenous and heterogeneous systems are surveyed and commented on their significance. A main focus is laid on the utility of the ΔΛ isomerism of octahedral metal complexes as a chiral source. The reported works demonstrate that chiral metal complexes are effective as a molecular element in achieving varieties of functions such as chiral discrimination, chiral transfer, sensing and photoresponsive guests for biomolecules or liquid crystals. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
