ChemInform Abstract: Temperature Induced Phase Transition of CaMn0.5Zr1.5(PO4)3 Phosphate. |
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| Authors: | Maria Orlova Lukas Perfler Martina Tribus Petr Salnikov Benoit Glorieux Albina Orlova |
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| Abstract: | ![]()
In view of a known structural phase transition at 800—875 °C and the by 10 times increased luminescence of Mn2+ in the high‐temperature phase, low‐ (LT) and high‐temperature (HT) polymorphs of CaMn0.5Zr1.5(PO4)3 are prepared by sol—gel reaction of Mn(O‐Ac)2, Ca(NO3)2, ZrOCl2, and NH4H2PO4 in ethylene glycol followed by a final annealing (700 or 900 °C, 20 h, resp.). |
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| Keywords: | structure (solids and liquids) manganese, Mn calcium, Ca zirconium, Zr phosphorus, P luminescence, fluorescence (solids and liquids) |
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