| 含钒氧链阴离子的苯基三联吡啶钴配合物的合成、晶体结构及性质研究 |
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| 引用本文： | 杨 浩,陈文涛,冯玉泉,包晓玉,孙汝中.含钒氧链阴离子的苯基三联吡啶钴配合物的合成、晶体结构及性质研究[J].无机化学学报,2012,28(1):62-66. |
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| 作者姓名： | 杨 浩 陈文涛 冯玉泉 包晓玉 孙汝中 |
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| 作者单位： | 南阳师范学院化学与制药工程学院,南阳,473061 |
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| 基金项目： | 河南省教育厅自然科学基金 |
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| 摘 要： | 利用水热反应合成一种新型含钒氧链阴离子的苯基三联吡啶钴配合物{Co(PhTPY)2]V3O9.3H2O}n(PhTPY=4′-ph-2,2′∶6′,2″-terpyridine)。用元素分析、红外光谱和X-射线单晶衍射对其结构进行了表征,该配合物晶体属单斜晶系,C2/c空间群。同时测定了配合物的热稳定性、荧光性质和磁性质。
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| 关 键 词： | 钴配合物 晶体结构 磁性质 热稳定性 发光性质 |
Synthesis, Crystal Structure and Properties of Phenylterpyridyl Cobalt(m) Complex with Vanadium-Oxygen Chain Anion |
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| YANG Hao,CHEN Wen-Tao,FENG Yu-Quan,BAO Xiao-Yu and SUN Ru-Zhong.Synthesis, Crystal Structure and Properties of Phenylterpyridyl Cobalt(m) Complex with Vanadium-Oxygen Chain Anion[J].Chinese Journal of Inorganic Chemistry,2012,28(1):62-66. |
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| Authors: | YANG Hao CHEN Wen-Tao FENG Yu-Quan BAO Xiao-Yu and SUN Ru-Zhong |
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| Institution: | College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China,College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China,College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China,College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China and College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China |
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| Abstract: | A phenylterpyridyl cobalt(Ⅲ) complex with vanadium-oxygen chain anion {Co(PhTPY)2]V3O9·3H2O}n(PhTPY=4′-ph-2,2′∶6′,2″-terpyridine)was synthesized under the hydrothermal condition.The structure was characterized by elemental analysis,IR and X-ray single crystal diffraction.The crystal structure of the complex belongs to monoclinic system,space group C2/c.Thermal stability,photoluminescence property and magnetic susceptibility of the complex have been investigated.CCDC: 773121. |
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| Keywords: | cobalt(Ⅲ) complex crystal structure magnetic property thermal stability luminescence property |
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