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Mixed iron cobalt carbonyl sulphides

Authors:	Lázló Markó

Affiliation:	Department of Organic Chemistry, University of Chemical Engineering, H-8200 Veszprém Hungary

Abstract:	Two new mixed iron cobalt carbonyl sulphide clusters HFe₂(CO)₉S and Fe₂Co(CO)₈(NO)S have been prepared and characterized. The hydride complex undergoes acidic dissociation in polar solvents and the resulting anion was isolated as (Et₄N)[Fe₂Co(CO)₉S]. An efficient high pressure synthesis has been found for H₂Fe₃(CO)₉S.

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