Synthesis and characterisation of new triple halide-bridged mixed valence binuclear complexes of ruthenium and osmium |
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| Authors: | R. Contreras G.G. Elliot R.O. Gould G.A. Heath A.J. Lindsay T.A. Stephenson |
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| Affiliation: | Department of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ Great Britain |
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| Abstract: | Several isomers of the type [M2Cl5L4] (M = Ru, L = AsPh3, As(p-tol)3, As(p-PhCl)3, PEt2Ph, PMe2Ph; L2 = Ph2As(CH2)2AsPh2; M = Os, L = PPh3, AsPh3) have been synthesised by various routes and characterised by magnetic, ESR and electrochemical measurements, and for [(PEt2Ph)Cl2RuCl3Ru(PEt2Ph)3] by X-ray structural analysis. |
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| Keywords: | Author for correspondence. |
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