Unprecedented Barbier-type reactions catalysed by titanocene(III) |
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| Authors: | Rosales Antonio Oller-López Juan L Justicia José Gansäuer Andreas Oltra J Enrique Cuerva Juan M |
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| Affiliation: | Department of Organic Chemistry, Faculty of Sciences, University of Granada, Spain. |
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| Abstract: | Selective Barbier-type allylations, benzylations and propargylations of aldehydes and ketones can be carried out under extremely mild conditions employing titanocene(III) complexes as catalysts. In this way, chiral titanocene catalysts provided yields ranging from 50-80% of optically active products. |
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