Comparison of the equilibrium geometry of acetylene (C2H2) and disilyne (Si2H2) |
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| Authors: | Fumio Kawai Takeshi Noro Akinori Murakami Kimio Ohno |
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| Affiliation: | Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan |
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| Abstract: | The equilibrium geometry of disilyne is not linear, but is twisted. The potential surfaces of acetylene and disilyne have a critical internuclear distance between the central atoms, where the stable geometry changes from linear to twisted forms the R-dependence of the valence-shell electron energy causes the difference in the structure of the molecules. |
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