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微波加热液相均匀沉淀法制备纳米Sb2O3阻燃剂(英)
引用本文:朱广军,张 琳,罗 军,冯晓苗,杨绪杰,汪 信,陆路德.微波加热液相均匀沉淀法制备纳米Sb2O3阻燃剂(英)[J].无机化学学报,2004,20(12):1497-1501.
作者姓名:朱广军  张 琳  罗 军  冯晓苗  杨绪杰  汪 信  陆路德
作者单位:南京理工大学化工学院,南京,210094
基金项目:江苏省应用基础研究资助项目(No.BJ95218),南京理工大学科研发展基金资助项目(No.20000304)
摘    要:Antimonyoxide(Sb2O3)isanimportantadditiveflameretardant.Itisextensivelyusedinflameretar鄄danttreatmentofpolyolefine,polyvinylchloride,polyesterandtextiles.TheefficiencyofhalogenatedflameretardantcanbeenhancedbycooperatingwithSb2O3.ThesizeofSb2O3hasgreatef…

关 键 词:纳米Sb2O3阻燃剂  微波  均匀沉淀法  PE/EVA泡沫塑料

Preparation of Nanosized Sb2O3Flame Retardant by Liquid Phase Homogeneous Precipitation Method with Microwave Heating
ZHU Guang-Jun,ZHANG Lin,LUO Jun,FENG Xiao-Miao,YANG Xu-Jie,WANG Xin and LU Lu-De.Preparation of Nanosized Sb2O3Flame Retardant by Liquid Phase Homogeneous Precipitation Method with Microwave Heating[J].Chinese Journal of Inorganic Chemistry,2004,20(12):1497-1501.
Authors:ZHU Guang-Jun  ZHANG Lin  LUO Jun  FENG Xiao-Miao  YANG Xu-Jie  WANG Xin and LU Lu-De
Institution:College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094,College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094,College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094,College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094,College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094,College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094 and College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094
Abstract:Nanosized Sb2O3flame retardant with an average diameter of 30 nm was prepared by liquid phase homogeneous precipitation method with microwave heating. The preparation conditions were studied and optimized. Nanosized Sb2O3has been characterized by means of XRD, TEM, FTIR. FTIR results show that IR absorption of nanosized Sb2O3is red-shifted and strengthened. Microwave can promote the formation of nanosized Sb2O3. The concentration of urea affects particle size greatly. The nanosized Sb2O3was applied to flame retarding polyethylene (PE)/ethylene-vinyl acetate copolymer (EVA) foams. The mechanical properties and flame retardancy of the flame retarding PE/EVA foams were much improved.
Keywords:nanosized Sb2O3flame retardant  microwave  homogeneous precipitation method  PE/EVA foams
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