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Studies on the Synthesis of Eremophilane Sesquiterpenes. A Novel Entry into the Aristolane Ring System
Authors:James H Rigby  Jean-Pierre Denis
Institution:Department of Chemistry , Wayne State University , Detroit, MI, 48202
Abstract:Readily available tricyclo3.2.2.02,4]non-6-en-8-one is converted into the tricyclo ring system of the aristolane sesquiterpenes via an alkoxide accelerated 3, 3]-sigmatropic rearrangement.
Keywords:
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