Preparation of Aromatic Fluorides Via Diazotization and Photochemically Induced Fluoro-Dediazoniation of Aromatic Amines in Anhydrous Hydrogen Fluoride - Organic Base Solutions |
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| Authors: | Norihiko Yoneda Tsuyoshi Fukuhara Tetsuo Kikuchi Akira Suzuki |
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| Institution: | Department of Applied Chemistry, Faculty of Engineering , Hokkaido University , Sapporo, 060, Japan |
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| Abstract: | Fluoro-dediazoniation of aromatic diazonium ions, produced by the diazotization of the corresponding aromatic amines with NaNO2 in anhydrous hydrogen fluorides (AHF) - organic base solutions, was accelerated photochemically to afford Ar-F efficiently in AHF - organic base solutions in situ. |
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