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Regioselective Synthesis of Allyl Trimethylsilanes from Allylic Halides |
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| Authors: | Janice Gorzynski Smith Nina R Quinn Malini Viswanathan |
| Institution: | Carr Laboratory , Mount Holyoke College South Hadley , Massachusetts, 01075 |
| Abstract: | Treatment of an allylic halide 1 with a trimethylsilyl metal reagent affords either trans allyl trimethylsilane 4 or the regioisomeric allyl trimethylsilane 3 with proper choice of reaction conditions. |
| Keywords: | |