Aminohaloborane in Organic Synthesis. V.1 An Aldol-Type Condensation of Acetonitrile and Phenylacetonitrile with Benzaldehydes Using Secondary Aminodichloroborane |
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| Authors: | Tsutomu Sugasawa Tatsuo Toyoda |
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| Institution: | 1. Shionogi Research Laboratory, Shionogi &2. Co., Ltd. , Fukushima-ku, Osaka, 553, Japan |
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| Abstract: | 3-Phenyl-3-sec-aminopropionitriles (1) are not found in literature. We describe here a simple synthesis of 1 from acetonitriles (2) and benzaldehydes (3) using sec-aminodichloroboranes (4)2 and triethylamine (5). |
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