Phase-Transfer Catalytic Alkylation of Hydroperoxides: A Convenient Route to Mixed Dialkyl Peroxides |
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| Authors: | Jean Moulines Marie-Josèphe Bougeois Monique Campagnole Anne-Marie Lamidey Bernard Maillard Evelyne Montaudon |
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| Institution: | 1. Laboratoire de Chimie Appliquée , Université de Bordeaux I;2. Laboratoire de chimie Organique et Organométallique , URA 35, associé au CNRS 351 Cours de la Libération, F-33405 , Talence Cedex |
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| Abstract: | The solid-liquid phase transfer catalytic alkylation of hydroperoxides using solid potassium hydroxide as a base and TEBAC as a phase transfer catalyst is reported. When the alkylating agent is a primary bromide, this reaction represents a simple and quick method for the synthesis of mixed dialkyl peroxides in fair yields. |
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| Keywords: | Aryltriazoles thioisocyanate |
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