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Phase Transfer Catalyzed Peroxidation of Car Boxylic Acids with Potassium Persulfate
Authors:C S Pande  Neena Jain
Institution:Department of Chemistry , H.P. University , Summer Hill, Shimla, 171005, India
Abstract:Aqueous solution of potassium persulfate converts water-insoluble carboxylic acids in ether (or dichloromethane), to peracids in a yield of 80–90% under the catalytic influence of benzyltriethylammonium chloride (BTEAC) or polyethyleneglycol (PEG-400). The reaction is further catalyzed kinetically in presence of a sulfonated polymer.
Keywords:
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