Ruthenium-Catalyzed Allylic Substitution of Allylic Cyclic Carbonates |
| |
| Authors: | Suk-Ku Kang Dae-Yeun Kim Ryung-Kee Hong Pil-Su Ho |
| |
| Affiliation: | Department of Chemistry , Sung Kyun Kwan University , Natural Science Campus, Suwon, 440746, Korea |
| |
| Abstract: | Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh3)2Cl (5 mol %) afforded (E)-allylic alcohol and erythro-β-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to π-allyl ruthenium complex. |
| |
| Keywords: | |
|
|
