Regioselective Aromatic Monobromination of Alkyl Phenyl Ethers with NaClO2, NaBr,Mn(acac)3, and Montmorillonite K10 in Dichloromethane |
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Authors: | Masao Hirano Shigetaka Yakabe Hiroyuki Monobe Takashi Morimoto |
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Affiliation: | Department of Applied Chemistry, Faculty of Technology , Tokyo University of Agriculture and Technology , Koganei, Tokyo, 184, Japan |
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Abstract: | Regioselective and high-yielding nuclear monobromination of aromatic ethers can be accomplished with a combination of NaClO2, NaBr, and Mn(acac)3 catalyst in dichloromethane under mild and neutral conditions with the aid of Montmorillonite K10. |
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