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Efficient Oxidation of Sulfides Catalyzed by Transition Metal Salts with Molecular Oxygen in the Presence of Aldehydes
Authors:Guoqiang Song  Fan Wang  Hao Zhang  Xiaoling Lu  Chen Wang
Affiliation:Department of Applied Chemistry , Jiangsu Institute of Petrochemical Technology , Changzhou, 213016, P.R. China
Abstract:Oxidation of sulfides to sulfoxides and sulfones was achieved in moderate to high yields with a good selectivity, by using Fe2O3, MnO2, Cu(OH)2 and Cu(OAc)2 as catalyst, with molecular oxygen in the presence of isovaleraldehyde under mild conditions.
Keywords:Aryl halides  Nucleophilic substitution  Solvent free  Montmorillonite K10
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