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A Novel Allylic Oxidation Using a Combination of Formic Acid and Selenium Dioxide
Authors:Kimiyuki Shibuya
Institution:Tokyo Research Laboratories , Kowa Co., Ltd , 2-17-43 Noguchi-cho, Higashimurayama, Tokyo, 189, Japan
Abstract:A combination of formic acid and selenium dioxide in dioxane has been found to be an efficient system for the allylic oxygenation of olefins, in particular for sterically hindered ones, leading to the corresponding allylic alcohols or formates.
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