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Convenient Synthesis of 1,3,6-Triene Systems Through Alkylation of 3-Methyl-3-sulfolene.
Authors:T Subramanian  R Padmakumar  Sujata V Bhat
Institution:Department of Chemistry , Indian Institute of Technology , Bombay , India
Abstract:Abstract: Various 1,3,6-triene systems have been synthesised through alkylation of 3-methyl-3-sulfolene with conjugated aldehydes followed by silylation and subsequent desulfonylation. A new route to synthesis of (+/?)-α-chamigrene, isofokienol and 5-hydroxy-α-farnesene has been described.
Keywords:
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