Convenient Synthesis of 1,3,6-Triene Systems Through Alkylation of 3-Methyl-3-sulfolene. |
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Authors: | T Subramanian R Padmakumar Sujata V Bhat |
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Institution: | Department of Chemistry , Indian Institute of Technology , Bombay , India |
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Abstract: | Abstract: Various 1,3,6-triene systems have been synthesised through alkylation of 3-methyl-3-sulfolene with conjugated aldehydes followed by silylation and subsequent desulfonylation. A new route to synthesis of (+/?)-α-chamigrene, isofokienol and 5-hydroxy-α-farnesene has been described. |
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