Palladium Catalysed Reactions of Baylis-Hillman Products: Synthesis of Some Useful Intermediates |
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| Authors: | R Kumareswaran Yashwant D Vankar |
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| Institution: | Department of Chemistry , Indian Institute of Technology , Kanpur, 208 016, INDIA |
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| Abstract: | Acetates derived from Baylis-Hillman products were reacted with sodio dimethyl (or diethyl) malonate under Pd(0) catalysis to form E olefins as the major products. Likewise, the Heck reaction with these acetates as well as with the corresponding alcohols form a variety of useful intermediates which include trisubstituted olefinic compounds and α-benzyl β-keto esters. |
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