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Sequential [2+2] Photocycloaddition and Rearrangement to Substituted Cyclopentanone. A formal Synthesis of Planococcyl Acetate
Authors:Debasis Patra  Subrata Chosh
Institution:Department of Organic Chemistry , Indian Association for the Cultivation of Science, Jadavpur , Calcutta, 700 032, India
Abstract:An extremely short synthesis of 2,2-dimethyl-3-hydroxymethyl cyclopentanone 2 (R1 = R2 = Me), an advanced intermediate in the synthesis of the pheromone planococcyl acetate 3, is described.
Keywords:1  3‐Disubstituted ureas  diisocynates  isocyanates  tertiary amines  thioisocyanates
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