An Unusual Reaction of Methyl 3,5-Dimethoxybenzoate with Thallium(III)Trinitrate - Trifluoro Acetic Acid |
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| Authors: | B. S. Bajwa S. V. Bhat J. Reden N. J. De Souza H. W. Fehlhaber |
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| Affiliation: | 1. Hoechst Pharmaceuticals Limited , Mulund, Bombay, 400 080, India;2. Hoechst AG. , Frankfurt, (M)-80, West Germany |
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| Abstract: | Thallium(III)trinitrate trihydrate (TTN) is known to be a useful and extremely versatile reagent in organic synthesis.1-5 Its use has been exploited mainly in oxidation and oxidative rearrangements of chalcones, aromatic ketones and phenols. In this communication, we report an unusual reaction of polyoxygenated methylbenzoates with TTN. |
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