Raman and ESR study of sol–gel materials from ZnO–TiO2–B2O3 system |
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| Authors: | BA Sava Adriana Diaconu Lucica Boroica Daniela Ursu T Visan M Elisa Alina Balu |
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| Institution: | aNational Institute of Glass, 47th Th. Pallady Str., Sect. 3, 032258, Bucharest, Romania;bPolytechnic University of Bucharest, Faculty of Applied Chemistry, 313th Spl. Independentei Str., S6, Bucharest, Romania;cNational Institute for Optoelectronics, Magurele, Bucharest, Romania;dInstitute of Physical Chemistry “I. G. Murgulescu”, Romanian Academy, 202th Spl. Independentei Str., S6, 060021, Bucharest, Romania |
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| Abstract: | The paper studies the materials from ZnO–TiO2–B2O3 ternary system, obtained by sol–gel method 1] and 2], starting from organic and inorganic precursors. The obtained samples are investigated by FTIR and Raman spectroscopy, which provide structural information, at molecular level. FTIR absorption maxima are identified and discussed according to literature data. Raman spectra are acquired by a Raman Jasco NRS-3100 spectrometer, at 532 nm wavelength and put in evidence characteristic vibration modes for all three oxide components. ESR spectra were plotted with the aid of a JES-FA 100-JEOL Japan spectrometer and titanium surrounding is investigated. |
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| Keywords: | FTIR measurements Raman spectroscopy Borates Titanates Electron spin resonance Sol– gels (xerogels) Medium-range order |
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