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Efficient Regio‐ and Stereoselective Conversions of Oxiranes and Aziridines into β‐(Nitrooxy)‐Substituted Alcohols and Amines by Using Bismuth Nitrate |
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| Authors: | Biswanath Das Maddeboina Krishnaiah Katta Venkateswarlu Vtukuri Saidi Reddy |
| Institution: | 1. Organic Chemistry Division‐I, Indian Institute of Chemical Technology, Hyderabad‐500 007, India, (phone: +?91‐40‐7193434;2. fax: +?91‐40‐7160512) |
| Abstract: | Oxiranes and aziridines efficiently undergo ring opening with bismuth nitrate at room temperature to furnish the corresponding β‐(nitrooxy)‐substituted alcohols and amines respectively. The conversions are highly regio‐ and stereoselective and afford the nitrooxy‐compounds in excellent yields within a short period of time. |
| Keywords: | Alcohols Amines Oxiranes Aziridines Bismuth nitrate Regioselective synthesis Stereoselective synthesis Nitrooxy compounds |