| CRYSTAL AND MOLECULAR STRUCTURE OF BIS(L-VALINATO)COPPER(II) MONOHYDRATE Cu[(CH_3)_2CHCH(NH_2)COO]_2·H_2O |
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| 摘 要： | <正> Mr=313.8, monocllnic, C2, a=21.255(4), b=9.567(4), c=7.399(1)A, β=108.8(1)°, V=1423.8A3, Z=4, Dx=1.464 g.cm-3, MoKα , μ=15.496cm-1 , F(OOO) = 660, T=295K, final R=0.089 for 1644 observed reflections. Two amino acid ligands chelate to copper forming a planar-square configuration. An oxygen atom of water occupying the apical position makes the coordinating polyhedron of copper a square pyramid.
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CRYSTAL AND MOLECULAR STRUCTURE OF BIS(L-VALINATO)COPPER(II) MONOHYDRATE Cu[(CH_3)_2CHCH(NH_2)COO]_2·H_2O |
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| Abstract: | Mr=313.8, monocllnic, C2, a=21.255(4), b=9.567(4), c=7.399(1)A, β=108.8(1)°, V=1423.8A3, Z=4, Dx=1.464 g.cm-3, MoKα , μ=15.496cm-1 , F(OOO) = 660, T=295K, final R=0.089 for 1644 observed reflections. Two amino acid ligands chelate to copper forming a planar-square configuration. An oxygen atom of water occupying the apical position makes the coordinating polyhedron of copper a square pyramid. |
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