| Tris（2,2＇-bipyridyl） Ruthenium（Ⅱ） Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties |
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| 引用本文： | 魏辉,杜艳,康建珍,徐国宝,汪尔康.Tris（2,2＇-bipyridyl） Ruthenium（Ⅱ） Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties[J].中国化学,2007,25(2):159-163. |
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| 作者姓名： | 魏辉 杜艳 康建珍 徐国宝 汪尔康 |
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| 作者单位： | [1]State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun, Jilin 130022, China [2]Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （Nos. 20335040 and 20427003）. |
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| 摘 要： | An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis（bipyridyl）-4,4＇-dicarboxy-2,2＇-bipyridyl-ruthenium to （3-aminopropyl）-triethoxysilane. The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol-gel modified indium tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior.
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| 关 键 词： | 电化学 合成方法 硅 钌 共价 催化 水解 |
| 修稿时间： | 2006-05-092006-11-09 |
Tris(2,2′‐bipyridyl) Ruthenium(II) Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties |
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| Hui Wei,Yan Du,Jian‐Zhen Kang,Guo‐Bao Xu,Er‐Kang Wang.Tris(2,2′‐bipyridyl) Ruthenium(II) Doped Silica Film Modified Indium Tin Oxide Electrode and Its Electrochemiluminescent Properties[J].Chinese Journal of Chemistry,2007,25(2):159-163. |
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| Authors: | Hui Wei Yan Du Jian‐Zhen Kang Guo‐Bao Xu Er‐Kang Wang |
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| Institution: | 1. State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, China;2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China;3. Fax: 0086‐0431‐85689711;4. Tel.: 0086‐0431‐85262003 |
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| Abstract: | An approach was reported to synthesize silica hybridized ruthenium bipyridyl complex through amidation reaction by covalent attachment of bis(bipyridyl)‐4,4′‐dicarboxy‐2,2′‐bipyridyl‐ruthenium to (3‐aminopropyl)‐triethoxy‐ silane. The hybrid complex then was gelatinized through acid catalytic hydrolysis method and a sol‐gel modified indium tin oxide electrode was prepared via spin coating technique. As prepared indium tin oxide electrode possesses good stability therein with excellent electrochemiluminescence behavior. |
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| Keywords: | electrochemiluminescence sol-gel modified electrode |
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