| Synthesis and Electrospray Ionization Mass Spectra of N-（1,3, 2-Dioxaphosphorinan-2-ylmethyl）thiophosphoramidates |
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| 引用本文： | 苗志伟,傅翠蓉,王彬,崔占伟,张建锋,陈茹玉.Synthesis and Electrospray Ionization Mass Spectra of N-（1,3, 2-Dioxaphosphorinan-2-ylmethyl）thiophosphoramidates[J].中国化学,2007,25(9):1344-1348. |
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| 作者姓名： | 苗志伟 傅翠蓉 王彬 崔占伟 张建锋 陈茹玉 |
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| 作者单位： | State Key Laboratory of Elemento-organic Chemistry, Research Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China |
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| 基金项目： | Project supported by Nankai University （No. J02044） and Tianjin Natural Science Foundation （No. 07JCZDJC04800）. |
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| 摘 要： | N-（1,3,2-Dioxaphosphorinan-2-ylmethyl）thiophosphoramidates were synthesized and determined by NMR spectra and positive ion electrospray ionization mass spectrometry （ESI-MS） in conjunction with tandem mass spectrometry （MS/MS）. The fragmentation pathways were investigated. The results show that these characteristic ions in ESI mass spectra are useful in the structural determination of N-（1,3,2-dioxaphosphorinan-2-ylmethyl）- thiophosphoramidates.
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| 关 键 词： | 电离化 光谱作用 共轭化合物 测量方法. |
| 修稿时间： | 2006-09-12 |
Synthesis and Electrospray Ionization Mass Spectra of N-（1,3, 2-Dioxaphosphorinan-2-ylmethyl）thiophosphoramidates |
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| MIAO Zhi-Wei, FU Cui-Rong,WANG Bin, CUI Zhan-Wei, ZHANG Jian-Feng, CHEN Ru-Yu.Synthesis and Electrospray Ionization Mass Spectra of N-（1,3, 2-Dioxaphosphorinan-2-ylmethyl）thiophosphoramidates[J].Chinese Journal of Chemistry,2007,25(9):1344-1348. |
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| Authors: | MIAO Zhi-Wei FU Cui-Rong WANG Bin CUI Zhan-Wei ZHANG Jian-Feng CHEN Ru-Yu |
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| Institution: | State Key Laboratory of Elemento-organic Chemistry, Research Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | N‐(1,3,2‐Dioxaphosphorinan‐2‐ylmethyl)thiophosphoramidates were synthesized and determined by NMR spectra and positive ion electrospray ionization mass spectrometry (ESI‐MS) in conjunction with tandem mass spectrometry (MS/MS). The fragmentation pathways were investigated. The results show that these characteristic ions in ESI mass spectra are useful in the structural determination of N‐(1,3,2‐dioxaphosphorinan‐2‐ylmethyl)thiophosphoramidates. |
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| Keywords: | ESI-MS N-（1 3 2-dioxaphosphorinan-2-ylmethyl）thiophosphoramidate conjugate tandem mass spectrometry |
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